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In this study, two high value biomaterials, Bacterial cellulose (BC) and Poly vinyl alcohol (PVA) was blended to form a new nanocomposite with the help of eleetrospinning technology.Homopolymer BC and PVA solutions were produced by dissolving the polymers in their common solvent, DMAc/LiCl.The two separately solutions then were mixed at room temperature.Afterward, the blends were electrospun by applying electrical field at room temperature.