4-硫代胸腺嘧啶激发态结构及动力学研究

来源 :第十五届全国化学动力学会议 | 被引量 : 0次 | 上传用户:yzl1983523
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  2-硫代胸腺嘧啶激发态动力学有广泛的实验和理论计算研究[1].Cui等人开展了CASSCF计算研究,提出了三条可能的激发态弛豫路径[2]:本文采用共振拉曼光谱技术,结合CASSCF计算方法,探究4-硫代胸腺嘧啶和2-硫代胸苷的激发态弛豫路径,以探究三条弛豫通道在不同硫代胸腺嘧啶激发态衰变动力学中的作用以及溶剂效应.
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