A Novel Titanium Complex Based on the Ethylene Linked Amidinate-Amido Ligand: Synthesis, Characteriz

来源 :中国化学会第十三届全国有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户:lf7891
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  In recent years,ethylene polymerization based on group 4 metal catalysts has been one of the most exciting developments in the area of catalysis,organometallic chemistry and polymer science,of which nitrogen chelating systems have attracted much attention1.Our group reported a series of group 4 metal amidinate,guanidinate,η3-azaallyl and mixed amidinate-amido complexes,and all of them exhibited moderate to good catalytic activities2.As a continuation of our research,a novel titanium complex bearing the ethylene linked amidinate-amido ligand was developed.
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