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采用一步法合成新型离子液聚合物,并以聚合物作为炭材料的前驱体。这种新型离子液聚合物的特征包括:聚合无需添加引发剂,聚合引入的阴离子能够控制材料的微孔大小。以含Cl-的离子液聚合物为前驱体合成的炭材料具有较小的比表面积(47m2/g),而以含较大(三氟甲基磺酰基)亚胺基阴离子的离子液聚合物为前驱体合成的炭材料具有较大的比表面积(595m2/g)。含二氰胺阴离子的离子液聚合物为前驱体合成的炭材料的比表面积为30m2/g。
A one-step synthesis of a new type of ionic liquid polymer, and polymer as carbon precursor material. The characteristics of this new ionic liquid polymer include: Polymerization Without the addition of an initiator, the anion introduced by polymerization can control the pore size of the material. The carbon material synthesized with Cl- containing ionic liquid polymer as a precursor has a smaller specific surface area (47 m2 / g), while the ionic liquid polymer containing a larger (trifluoromethylsulfonyl) iminium anion The carbon material synthesized for the precursor has a larger specific surface area (595m2 / g). The dicyandiamide anion-containing ionic liquid polymer is a precursor carbon material synthesized by the specific surface area of 30m2 / g.