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应用热动力学１．５级反应的时间变量法，在２０℃和３０℃下研究了表面活性剂复配混合胶束溶液中，以ＮａＨＳＯ３为单组分引发剂的丙烯酰胺聚合反应．结果表明，阳、阴与两性离子表面活性剂复配混合胶束体系（ＣＴＡＢ／ＬＳＳ，ＴＴＡＢ／ＬＳＳ，ＳＤＳ／ＬＳＳ）对聚合反应有明显的催化作用，非与阳离子表面活性剂复配混合胶束体系（Ｂｒｉｊ３５／ＣＴＡＢ，Ｂｒｉｊ３５／ＴＴＡＢ，Ｂｒｉｊ３５／ＤＴＡＢ）对该反应有小的催化作用，Ｂｒｉｊ３５／ＳＤＳ混合胶束体系对反应有禁阻作用．这些作用是由于表面活性剂胶束的Ｓｔｅｒｎ层影响了引发剂ＨＳＯ－３生成自由基的反应．
The thermodynamic 1.5-step reaction time-varying method was used to study the acrylamide polymerization with NaHSO3 as a one-component initiator in the surfactant mixed micellar solution at 20 ℃ and 30 ℃. The results showed that the mixed micellar system (CTAB / LSS, TTAB / LSS, SDS / LSS) with cationic, anionic and zwitterionic surfactants could obviously catalyze the polymerization. Brij35 / CTAB, Brij35 / TTAB, Brij35 / DTAB had a small catalytic effect on the reaction, Brij35 / SDS mixed micelles system had a blocking effect on the reaction. These effects are due to the influence of the Stern layer of the surfactant micelles on the radical-generating reaction of the initiator HSO-3.