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The X-ray single-crystal structure analyses have been determined for two metal imidazole chlorides: [Fe(Im)6]Cl2(4H2O 1 and [CuCl(Im)4]Cl 2 (Im ( imidazole). The red crystal of compound 1 is of triclinic, space group Pī with Mr = 607.31 (C18H32Cl2FeN12O4)