Novel hybrids of Cu~(2+) ternary complexes of salicylidene-amino acid Schiff base with phenanthrolin

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:huangyqing
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Four Cu~(2+) complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline(Phen) or 2,2’- bipyridine(Bipy) were successfully intercalated in interlayer galleries of Mg/Al-NO_3-layered double hydroxide(LDH) by the swelling-restored method.The hybrids were characterized by elemental analysis,X-ray diffraction,FT-IR spectra,UV-vis DRS,TG-DTA and SEM observation.Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra,cyclic voltammograms and luminescence spectra. Four Cu 2+ complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline (Phen) or 2,2’-bipyridine (Bipy) were successfully intercalated in interlayer galleries of Mg / Al-NO 3-layered double hydroxide (LDH) by the swelling-restored method.The hybrids were characterized by elemental analysis, X-ray diffraction, FT-IR spectra, UV-vis DRS, TG- DTA and SEM observation .Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra, cyclic voltammograms and luminescence spectra.
其他文献
为评价类固醇激素受体状态与盆腔及主动脉旁淋巴结情况间的关系,对1985年1月~1991年3月间在衣阿华大学医院就诊的235例临床Ⅰ期子宫内膜腺癌患者进行回顾性分析。包括年龄、
广州铁路(集团)公司科研所、长沙机务段星光器材厂、张家界机务段1990年研制成功NJ—1调速器试验台,先后在张家界、广州、徐州北、株洲、襄樊北、南口、武昌南、徐州南、上
由上海市城市规划设计研究院等单位承担的《上海城市轨道交通模式研究》,最近通过专家评审。这项研究在对国外大城市轨道系统进行充分考证,对上海市情进 Shanghai Urban Pl
一、选择题 (本题满分 3 6分 ,每小题 3分 )1 .关于x的方程x2 +(k2 -4)x+(k-1 ) =0的两实数根互为相反数 ,则k值为 (  ) .A .1   B .2   C .-2   D .2或 -22 .已知
广西图书馆学会第五届理事会理事名单(46名,以姓氏笔划为序)方金修韦弦韦任平韦保平王继明王雪光区克莎左厚尧龙长生卢永容汤坤华刘强林苏正明李建光李冠盛李家全李晶心李锡初杨万
Co/SiO_2 and zirconium promoted Co/Zr/SiO_2 catalysts were prepared using dielectric-barrier discharge(DBD) plasma instead of the conventional thermal calcinati
本文根据盘石头水库溢洪道工程开挖爆破经验总结,提出了深孔爆破产生大块石的主要原因,及降低大块率的有效技术措施。总结了复杂结构建筑物采用预裂爆破技术的成功经验。 Ba
为比较妊娠期24周前肾盂肾炎门诊及住院治疗的安全性及有效性,采取随机对照方法,选择1991年4月~1993年7月120例妊娠合并肾盂肾炎患者,行60例一组。二组经产状态、体温、孕龄
话题作文提倡“三自”原则,即题目自拟、文体自选、立意自主,鼓励同学们解放思想,张扬个性,写出极具个性化的作文来。从2003年全国各地中考作文来看,考生的作文立意还有所欠
More people around the world are becoming too fat.The World Heart Federation in Geneva,Switzerland,re-ports that the number of overweight and obese people is i