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研究了双(对甲苯磺酸)2,4-已二炔-1,6-二醇酯(TS)及其不同聚合程度聚合物在100K-300K温度范围内的热电行为。在沿分子堆砌方向上观察到了他们的热电电流,并在相应于他们相变处呈现有热电电流峰。根据电流峰对应的温度绘制了TS-PTS体系的相图。
The thermoelectric properties of 2,4-hexadiyn-1, 6-diol (TS) bis (p-toluenesulfonate) and its polymers with different polymerization degrees in the temperature range of 100K-300K were studied. Their pyroelectric currents were observed in the molecular packing direction and the thermoelectric current peaks appeared at the corresponding phase transitions. The phase diagram of TS-PTS system is plotted based on the temperature corresponding to the current peak.