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A new metal-organic network, [Cd(CH_3OH)_2(epa)]_n(1), was synthesized from an achiral coupled cinnamic acid, 3,3?-((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))diacrylic acid(H_2epa), and Cd(NO3)2·4H2O under solvothermal conditions. The complex crystallizes in orthorhombic, space group P2_12_12 with a = 9.8286(8), b = 21.0004(16), c = 5.5169(4) ?, V = 1138.71(15) ?~3, M_r = 528.81, D_c = 1.542 Mg/cm~3, F(000) = 536, Z = 2, the final R = 0.0345 and wR = 0.1101 for 2006 observed reflections(I > 2σ(I)). In 1 the epa~(2+) anions alternately bridge the Cd(II) cations to form a one-dimensional(1D) infinite homochiral helical chain of [Cd(epa)]n. The chiral homohelical chains via hydrogen bonds formed a two-dimensional(2D) network. The photoluminescence of 1 was also investigated in solid state at ambient temperature.
A new metal-organic network, [Cd (CH_3OH) _2 (epa)] _ n (1), was synthesized from an achiral coupled cinnamic acid, 3,3? - The complex crystallizes in orthorhombic, space group P2_12_12 with a = 9.8286 (8), b = 21.0004 (16), (2,1-phenylene) diacrylic acid cm 3, F (000) = 536, Z = 2, the final R = 0.0345 and wR = In 1 the epa ~ (2+) anions alternately bridge the Cd (II) cations to form a one-dimensional (1D) infinite homochiral helical chain of [Cd (epa) )] n. The chiral homogenous chains via hydrogen bonds formed a two-dimensional (2D) network. The photoluminescence of 1 was also investigated in solid state at ambient temperature.