Determination of the acid dissociation constants of N-carboxymethyl-N-(p-hydroxy phenyl carbamoylmet

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The acid dissociation constants of N-carboxymethyl-N-(p-hydroxy phenyl carbamoyl-methyl)-2,3-dihydroxy-5-carbomethoxy benzylamine(CHDCB) and the stability constants of its 1:1complexes with alkaline earth, Cd(Ⅱ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ), Fe(Ⅲ),Th(Ⅳ)and U(Ⅵ)ionshave been determined at 25.0±0.1℃ and at an ionic strength of 0.1(KNO_3)by pH titration method.The probable coordination sites have also been discussed. The acid dissociation constants of N-carboxymethyl-N- (p-hydroxy phenyl carbamoyl-methyl) -2,3- dihydroxy-5-carbomethoxy benzylamine (CHDCB) and the stability constants of its 1: 1 complexes with alkaline earth, Cd (Ⅱ), Cu (Ⅱ), Zn (Ⅱ), Fe (Ⅲ), Th (Ⅳ) and U (Ⅵ) ions have been determined at 25.0 ± 0.1 ℃ and at an ionic strength of 0.1 (KNO3) by pH titration method. The probable coordination sites have also been discussed.
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