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用有机分析试剂制备活动载体离子电极膜,是有机试剂用于电分析化学的重要发展方向。以研究中性载体著称的瑞士Simon学派,最近发表了关于中性载体有机化合物用于离子电极的综述,中性载体类有机试剂目前基本上只能用于阳离子选择电极的制备。而另一方面,荷电载体型的有机试剂,除烷基磷酸酯等少数几种用于钙等阳离子电极外,大部分是用于制备阴离子选择性电极的。本文拟对用于制备阴离子选择性电极的有机分析试剂的发展概况,作一简要的综述。
Preparation of active carrier ion electrode membrane with organic reagent is an important development direction of organic reagent for electroanalytical chemistry. The Swiss school of Simon, known for studying neutral carriers, recently published a review on the use of neutral carrier organic compounds for ionic electrodes. Currently, neutral carrier organic reagents are currently only available for the preparation of cation selective electrodes. On the other hand, charge-carrier-type organic reagents, except alkyl phosphate and a few other types of cationic electrodes such as calcium, are mostly used to prepare anion-selective electrodes. This article intends to make a brief overview of the development of organic reagents for the preparation of anion selective electrodes.