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The title compound ZnS-6(C-{12}H-8N-2) was obtained by reaction of zinic powder with sulfur and 1,10|phenathtroline in DMF solvent, and its structure has been determined by single crystal X|ray diffraction analysis. The crystal data for the compound: triclinic, $P1, Z=2, a=8.159(2), b=9.485(2), c=11.997(2), α=110.00(3)°,β=99.22(3)°, γ=100.57(3)°, V=832+3, D-c$=1.748g/cm+3, μ (M-o K-α )=0.2219 cm+{-1}, F (000)=440. The structure was refined to $R=0.0723$ and $R-w=0.0865$ for 1427 independent observed reflections. The tilte crystal consists of a discrete molecules, in which the core of ZnS-2N-2 shows a distorted tetrahedral geometry.
The title compound ZnS - 6 (C - {12 } H - 8N - 2) was obtained by reaction of zinic powder with sulfur and 1,10 | phenathtroline in DMF solvent , and its structure has been determined by a single crystal X | ray diffraction analysis. The crystal data for the compound: triclinic, $ P1, Z = 2, a = 8.159 (2), b = 9.485 α = 110.00 (3) °, β = 99.22 (3) °, γ = 100.57 (3) °, V = 832 + 3, D - c $ = 1.748g / cm + 3, μ (M - o K - α) = 0.2219 cm + {-1 }, F (000) = 440. The structure was refined to $ R = 0.0723 $ and $ R - w = 0.0865 $ for 1427 independent observed reflections. The tilte crystal consists of a discrete molecules, in which the core of ZnS - 2N - 2 shows a distorted tetrahedral geometry.