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One-pot solvothermal reaction of transition metal Cd(Ⅱ) salt with (2E,2’E)-3,3’-((propane-1,3-diylbis(oxy))bis(2,1-phenylene))diacrylic acid (H2ppa) and 1,10-phenanthroline (phen) generates a meso-helicate, [Cd(ppa)(phen)(H2O)]2, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent property. The complex crys-tallizes in monoclinic, space group P21/c with a = 13.4622(7), b = 24.8452(12), c = 8.9314(4) , β = 97.564(1)o, V = 2961.3(2) 3, C66H56N4O14Cd2, Mr = 1353.97, Dc = 1.518 g/cm3, μ(MoKα) = 0.789 mm-1, F(000) = 1376, Z = 2 , the final R = 0.0248 and wR = 0.0667 for 4673 observed reflections (I > 2σ(I)). The 1-D supramolecular chain is built up from the complex by π-π stacking interactions, and inter-chain hydrogen bonds prompt the 1-D chains into a 2-D layer. The title compound shows strong photoluminescence with emission maximum at λ = 445 nm upon λEx, max = 240 nm.
One-pot solvothermal reaction of transition metal Cd (Ⅱ) salt with (2E, 2’E) -3,3 ’- (propane- 1,3-diylbis (oxy) bis acid (H2ppa) and 1,10-phenanthroline (phen) generates a meso-helicate, [Cd (ppa) (phen) (H2O)] 2 and characterized by single-crystal X-ray diffraction, elemental analyzes, IR spectroscopy, the complex crys-tallizes in monoclinic, space group P21 / c with a = 13.4622 (7), b = 24.8452 (12), c = 8.9314 (4) 2961.3 (2) 3, C66H56N4O14Cd2, Mr = 1353.97, Dc = 1.518 g / cm3, μ (MoKα) = 0.789 mm -1, F (000) = 1376, Z = 2, final R = 0.0248 and wR = for 4673 observed reflections (I> 2σ (I)). The 1-D supramolecular chain is built up from the complex by π-π stacking interactions, and inter-chain hydrogen bonds prompt the 1-D chains into a 2-D layer The title compound shows strong photoluminescence with emission maximum at λ = 445 nm upon λEx, max = 240 nm.