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The crystallization behavior, rheological behavior, mechanical properties and microstructures of injection molded isotactic polypropylene(i PP), polypropylene random copolymer(co-PP) and i PP/co-PP blends were investigated. Differential scanning calorimetry(DSC) and dynamic rheological analysis illustrated that i PP and co-PP were compatible in the blends and co-PP uniformly dispersed in the i PP phase. Polarizing optical microscope(POM) was adopted to observe the crystal size and morphology evolution. The results of mechanical properties and scanning electron microscopy(SEM) indicated that the crystal size of i PP in i PP/co-PP blends(10 wt% co-PP + 90 wt% i PP and 30 wt% co-PP + 70 wt% i PP) radically decreased after the incorporation of co-PP. During crystallization, the molecular chain segments of co-PP could penetrate i PP spherulites and form a network-like crystalline structure. The network-like crystal structure could effectively transmit stress and consume more energy to overcome intermolecular forces to resist stretching. In this way, the strength would improve to a certain degree. The impact fracture mechanism of i PP/co-PP blends is quasi ductile fracture by multiple crazes. Our work discovered that the blends containing 10 wt% and 30 wt% of co-PP exhibited prominent toughness and reinforcement.
The crystallization behavior, rheological behavior, mechanical properties and microstructures of injection molded isotactic polypropylene (i PP), polypropylene random copolymer (co-PP) and i PP / co-PP blends were investigated. Differential scanning calorimetry illustrated that i PP and co-PP were compatible in the blends and co-pp uniformly dispersed in the i PP phase. Polarizing optical microscope (POM) was adopted to observe the crystal size and morphology evolution. microscopy (SEM) indicated that the crystal size of i PP in i PP / co-PP blends (10 wt% co-PP + 90 wt% i PP and 30 wt% co-PP + 70 wt% i PP) the incorporation of co-PP. During crystallization, the molecular chain segments of co-PP could penetrate i PP spherulites and form a network-like crystalline structure. The network-like crystal structure could substantially transmit stress and consume more energy to overc In this way, the strength would improve to a certain degree. The impact fracture mechanism of i PP / co-PP blends is quasi ductile fracture by multiple crazes. Our work discovered that the blends containing 10 wt% and 30 wt% of co-PP Featured prominent toughness and reinforcement.