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1951年Kirchner等第一个在薄层上探索对石油的分离,是在氧化铝和硅胶与淀粉石膏紧密胶合在玻璃板上的薄层上进行的。但在这前后,薄层色谱(TLC)用于石油产品添加剂分析方面的报道并不多见。直至1955年Holness和Stone详细报道了应用硅胶G薄层分离鉴别润滑油中添加剂之后,TLC作为石油产品添加剂的分离测定手段,才迅速地发展起来,并在石油化工的各个领域中逐步推广应用。
In 1951, Kirchner et al. First explored the separation of petroleum from thin layers by applying alumina and silica gel to a thin layer of starch gypsum closely bonded to a glass plate. However, before and after this, there are few reports on the TLC analysis of additives for petroleum products. It was not until 1955 that Holness and Stone reported in detail the separation and identification of additives in petroleum products by silica gel G TLC. As a separation and determination method for petroleum products, TLC developed rapidly and was gradually applied in various fields of petrochemical industry.