论文部分内容阅读
我们的“原子轨道概念及其图形表示”一文在《化学通报》刊登后,编辑部收到不少来稿来信,进行讨论或提出询问,所围绕的问题实质上涉及波函数的解释、量子力学的测量理论与本征值问题、轨道近似描述多体问题的真实性以及线性空间的表达方式等。的确,由于量子力学是一种描述微观物理世界(包括原子、分子)的独特的数学方案,所以对上述问题定性、形象描述不仅要牺牲数学的严格性,而且常常是不可能
After the publication of the “Atomic Orbital Concept and Its Graphic Representations” in the Chemical Bulletin, the editorial department received a great deal of contributions, discussed or inquired about the issues surrounding the wave function in essence. Quantum mechanics Measurement theory and eigenvalue problems, orbit approximation to describe the authenticity of multi-body problems and the expression of linear space. Indeed, since quantum mechanics is a unique mathematical solution for describing the microscopic physical world (including atoms, molecules), characterizing the above problem requires not only sacrificing mathematical rigor but often impossible