Surface Modified TiO_2 Nanoparticles——an Effective Anti-wear and Anti-friction Additive for Lubricat

来源 :China Petroleum Processing & Petrochemical Technology | 被引量 : 0次 | 上传用户:hw565656
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The surface modified TiO_2 nanoparticles were prepared by using 12-hydroxystearic acid chemically modified on the TiO_2 surface. The average size of the TiO_2 particles is about 30 nm. The optimum ratio of tetrabutyl titanate to 12-hydroxystearic acid was 1/0.5. The bonding form between 12-hydroxystearic acid and TiO_2 nucleus was investigated by FTIR, DSC, TGA and XRD techniques. The lubricating grease containing the surface modified TiO_2 nanoparticles possesses excellent anti-wear and anti-friction properties. Compared with the grease without TiO_2, the PB value can be increased by 52% as the best performance of the grease containing surface modified TiO_2 nanoparticles, while the friction coefficient can be reduced by 33% with the addition of a small amount of TiO_2 nanoparticles, and meanwhile the wear scar diameter decreases by 25%. The surface modified TiO 2 nanoparticles were prepared by using 12-hydroxystearic acid chemically modified on the TiO 2 surface. The average size of the TiO 2 particles is about 30 nm. The optimum ratio of tetrabutyl titanate to 12-hydroxystearic acid was 1 / 0.5. Form between 12-hydroxystearic acid and TiO_2 nucleus was investigated by FTIR, DSC, TGA and XRD techniques. Compared with the grease without TiO_2, the PB The friction can be reduced by 33% with the addition of a small amount of TiO 2 nanoparticles, and meanwhile the wear scar diameter decreases by 25 %.
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