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波兰凱米拉(W.Kemula)于1952年把色层法与极谱法联用并定名为色层极谱,他们一直进行着系统的研究并建立了自已的学派。实际上,色层极谱与离子交换极谱可以认为是极谱自动分析的特例,不过对指示电极、参此电极等方面的要求没有后者严格,只是把流经色层柱(或离子交换柱)的溶液接在适于自动分析的电解池中进行短时间的连续记录。用极谱法可以直接记录出色层法(或离子交换法)的前流分析、洗脱分析和置换分析曲线。我们试用了滴汞电极为指示电极,层汞电极为参比电极,将电压加在能得出各离子的极限电流处,追踪记录在流经柱子前后过程中硒、碲、铜、镉、铅等离子极
W.Kemula in Poland in 1952, the chromatography method and the polarographic method and named the chromatography, they have been conducting a systematic study and established their own schools. In fact, chromatographic and ion exchange polarography can be considered as a special case of polarographic automatic analysis, but not for the indicator electrode, reference electrode, etc. The latter is not strict, except that the color column (or ion exchange Column) was connected to the electrolysis cell for automatic analysis for a short period of continuous recording. Polarographic method can be directly recorded by the pre-flow chromatography (or ion exchange method) before the flow analysis, elution analysis and displacement analysis curve. We tried the drop mercury electrode as the indicator electrode and the mercury electrode as the reference electrode. The voltage was added to the limit current at which each ion could be derived, and the selenium, tellurium, copper, cadmium and lead Plasma pole