膜富集甲硫醇实验研究

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利用CSM膜对甲硫醇/空气体系进行富集实验,考察原料气浓度、流量、膜两侧压力差、操作温度对甲硫醇的渗透速率和富集率的影响。实验结果表明:随着原料气中甲硫醇浓度的增加,渗透速率会随之增大,但是富集率先增大后减小;随着原料气流量的增加,甲硫醇的渗透速率减小而且富集率也明显下降;随着膜两侧压力差的增大,甲硫醇的渗透速率和富集率都随之增大;随着操作温度的升高,甲硫醇的渗透速率减小,富集率变化不大。当原料气操作温度为293.2K、甲硫醇的浓度为53ppm、膜两侧压力差为0.067MPa、流量为150L/h时,CSM膜对甲硫醇的富集效率可达13%。 The enrichment experiments of methanethiol / air system by CSM membrane were carried out to investigate the effect of feed gas concentration, flow rate, pressure difference on both sides of membrane, operating temperature on permeation rate of methanethiol and enrichment rate. The experimental results show that with the increase of methanethiol concentration in the feed gas, the permeation rate will increase, but the enrichment rate first increases and then decreases. With the increase of feed gas flow, the permeation rate of methanethiol decreases And the enrichment rate also decreased obviously. With the increase of pressure difference on both sides of the membrane, both permeation rate and enrichment rate of methanethiol increased. With the increase of operating temperature, the permeation rate of methanethiol decreased Small, enrichment rate changed little. When the operation temperature of the feed gas is 293.2K, the concentration of methanethiol is 53ppm, the pressure difference between the two sides of the membrane is 0.067MPa and the flow rate is 150L / h, the enrichment efficiency of the CSM membrane to methanethiol can reach 13%.
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