Frustrated Lewis Pair Catalysis:It Takes Two to Make a Thing Go Right

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Since the introduction of the concept of frustrated Lewis pair by Stephan in 2006,the frustrated Lewis pair (FLP) chemistry has evolved into a rich and fruitful research area which is largely responsible for the renaissance of main group chemistry in recent years.Among many applications of FLP,design of catalytic systems based on the concept of FLP,pioneered by Stephan,Chen and others,provides a powerful arsenal that has been applied to organic synthesis and polymerization.This article will highlight key advances in the development of FLP related catalysis.
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