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从热力学角度讨论了 ＣＩＭＳ中含不同官能团 Ｘ的系列有机化合物质子化分子 离子 ＲＸＨ＋脱中性分子反应随 ＰＡ（ＨＸ）的增加而减小的规律，用 Ｒ＝Ｃ４Ｈ９ 的系列化合物在ＣＩＭＳ实验中验证了上述结论．本文首次提出并通过对离子能量分 布的一般分析，说明了离子盒压力对官能团脱去反应的影响。
From the thermodynamic point of view, we discuss the regularity of the decrease of the RXH + deproteinization reaction of series of organic compounds with different functional groups X in CIMS with the increase of PA (HX) from CIMS experiments in CIMS The above conclusion. This paper presents for the first time and through the general analysis of the ion energy distribution, illustrates the ion box pressure on the removal of functional groups.