碳氢键的功能化反应是近年来有机化学的研究热点之一,选择性碳氢活化是其研究难点.在此类反应中,一般以有机溶剂为反应介质,而利用廉价、环境友好的水作为反应溶剂符合当前所倡导的“绿色”化学和低碳可持续发展的理念.综述了近年来水相催化的碳氢活化反应,包括含有sp-,sp~2-,sp~3-杂化的C—H键的功能化反应. The functional reaction of carbon-hydrogen bond is one of the hot topics in organic chemistry in recent years, and selective hydrogenation is the difficult point in its research.In this kind of reaction, the organic solvent is usually used as the reaction medium and the cheap and environment-friendly water As a reaction solvent, it is in line with the current concept of “green” chemistry and sustainable development of low carbon, which is currently advocated. In this paper, the recent advances in water-catalyzed hydrocarbon activation including sp-, sp 2-, sp 3- Functionalization of Hybrid C-H Bonds.