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A silver(I) complex [Ag(chlsp)2](CF3CO2),(chlsp=(E)-4-(4-chlorostyryl) pyridine),was synthesized by the reaction between AgCF3CO2 and chlsp in the anhydrous enthnol. The crystal structure of [Ag(chlsp)2](CF3CO2) was characterized by elemental analysis,IR and determined by using single crystal X-ray diffraction. The result shows that the complex crystallize in triclinic system,with space group P1,a=0.109 7(2) nm,b=0.111 7(2) nm,c=0.117 2(2) nm,α=73.60(3)°,β=85.03(3)°,γ=81.82(3)°,V=0.136 2(4) nm3,Z=2. The moleculars are connected by Ag…Ag and Ag…Cl interactions,resulting in a three-dimensional network.
A silver (I) complex [Ag (chlsp) 2] (CF3CO2), (chlsp = (E) -4- (4-chlorostyryl) pyridine) was synthesized by the reaction between AgCF3CO2 and chlsp in the anhydrous enthnol. structure of [Ag (chlsp) 2] (CF3CO2) was characterized by elemental analysis, IR and determined by using single crystal X-ray diffraction. The result shows that the complex crystallize in triclinic system, with space group P1, a = 0.109 7 (2) nm, b = 0.111 7 (2) nm, c = 0.1172 2 nm, α = 73.60 (3) °, β = 85.03 (3) °, γ = 81.82 (3) °, V = 0.136 2 (4) nm3, Z = 2. The moleculars are connected by Ag ... Ag and Ag ... Cl interactions, resulting in a three-dimensional network.