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用停流分光光度法研究了氯代四苯基卟啉铁 ( ) [Fe T(p- X) PPCl,X=H,CH3 ]与肼在二氯甲烷溶液中的反应动力学 ,求得了不同温度下反应的速率常数及活化参数 ,初步探讨了反应机理。
The kinetics of the reaction of chloro-tetraphenylporphyrin iron (FeT (p-X) PPCl, X = H, CH3] with hydrazine in methylene chloride solution was studied by the stop-flow spectrophotometry. Temperature reaction rate constants and activation parameters, preliminary study of the reaction mechanism.